High-sensitivity laser absorption measurements of broadband absorbers in the near-infrared spectral region.

We describe the development and characterization of a near-infrared diode-laser-based sensor to measure the vapor from trace gases having unstructured absorption spectra. The technique uses two equal amplitude-modulated laser beams, with the modulation of the two lasers differing in phase by 180 deg. One of the laser beams is at a wavelength absorbed by the gas [for these experiments, vapor is from pyridine (C(5)H(5)N)], and the second laser beam is at a wavelength at which no absorption occurs. The two laser beams are launched onto near-coincident paths by graded-index lens-tipped optical fibers. The mixed laser beam signal is detected by use of a single photodiode and is demodulated with standard phase-sensitive detection. Data are presented for the detection and measurement of vapor from pyridine (C(5)H(5)N) by use of the mixed laser technique. The discussion focuses on experimental determination of whether a compound exhibits unstructured absorption spectra (referred to here as a broadband absorber) and methods used to maximize sensitivity.